MJR_RA_553_500K

Table 1 Crystal data and structure refinement for MJR_RA_553_500K.
Identification code MJR_RA_553_500K
Empirical formula ILi7S7Si2
Formula weight 456.08
Temperature/K 500.0
Crystal system monoclinic
Space group P21/n
a/Å 14.9817(2)
b/Å 6.05780(10)
c/Å 15.1891(2)
α/° 90
β/° 105.7390(10)
γ/° 90
Volume/Å3 1326.82(3)
Z 4
ρcalcg/cm3 2.283
μ/mm‑1 3.368
F(000) 856.0
Crystal size/mm3 0.03 × 0.02 × 0.02
Radiation synchrotron (λ = 0.6889)
2Θ range for data collection/° 3.282 to 72.382
Index ranges -25 ≤ h ≤ 25, -9 ≤ k ≤ 10, -25 ≤ l ≤ 25
Reflections collected 26423
Independent reflections 6367 [Rint = 0.0684, Rsigma = 0.0604]
Data/restraints/parameters 6367/59/237
Goodness-of-fit on F2 1.063
Final R indexes [I>=2σ (I)] R1 = 0.0370, wR2 = 0.0945
Final R indexes [all data] R1 = 0.0472, wR2 = 0.1030
Largest diff. peak/hole / e Å-3 1.49/-1.11

 

Table 2 Fractional Atomic Coordinates (×104) and Equivalent Isotropic Displacement Parameters (Å2×103) for MJR_RA_553_500K. Ueq is defined as 1/3 of the trace of the orthogonalised UIJ tensor.
AtomxyzU(eq)
Si15848.5(3)3482.2(7)3913.9(3)25.85(10)
Si25801.4(3)3546.2(7)1506.8(3)25.17(10)
Li14969(3)9277(7)2473(3)58.3(10)
Li26891(4)7601(9)3037(4)71(2)
Li33459(6)2763(10)2132(5)70.5(18)
Li44710(10)8760(30)4602(11)69(3)
Li56714(13)8100(30)5335(11)67(4)
Li63368(11)3510(30)4511(11)64(4)
Li75934(7)3887(19)6194(6)65(3)
Li84848(9)-800(20)225(8)96(5)
Li96808(8)7950(30)536(9)68(4)
Li105853(7)3680(20)-759(6)63(3)
Li113253(10)3370(40)-339(12)68(5)
Li12500010000500071(6)
Li137010(20)8310(50)5066(16)65(6)
Li144330(30)-1730(50)720(30)73(10)
Li154300(20)8050(50)3950(20)74(4)
I13122.0(2)7429.1(2)1963.1(2)37.30(6)
S14526.5(4)2058.0(8)3662.1(4)34.01(10)
S26780.9(4)2413.6(7)5135.0(4)36.27(12)
S35743.6(4)6927.0(8)3886.1(3)35.60(11)
S46511.0(4)2305.3(7)2876.8(3)27.90(9)
S54461.7(4)2189.5(7)1102.6(4)31.75(10)
S66655.6(4)2359.0(7)723.3(4)34.22(11)
S75819.5(4)7000.9(7)1513.5(3)32.91(10)

 

Table 3 Anisotropic Displacement Parameters (Å2×103) for MJR_RA_553_500K. The Anisotropic displacement factor exponent takes the form: -2π2[h2a*2U11+2hka*b*U12+…].
AtomU11U22U33U23U13U12
Si127.6(2)24.7(2)24.6(2)-0.80(15)6.02(16)-0.74(16)
Si227.5(2)23.3(2)24.4(2)0.05(14)6.46(16)-1.12(15)
Li158(3)56(2)60(2)1(2)14.3(19)2(2)
Li241(4)114(7)54(4)0(2)6(3)-16(2)
Li364(4)85(4)67(4)18(3)25(3)24(3)
Li472(7)79(7)67(8)26(6)37(5)2(6)
Li577(7)80(10)38(7)6(7)8(5)-6(8)
Li648(7)60(7)58(8)-34(6)-28(6)13(5)
Li764(6)85(7)51(5)9(5)28(4)33(6)
Li899(9)97(9)69(7)-32(7)-14(6)38(8)
Li950(6)89(10)71(7)5(7)24(5)2(6)
Li1057(6)83(7)45(4)5(4)7(4)13(5)
Li1156(7)82(11)75(9)31(8)35(6)12(7)
Li1287(9)70(9)61(11)35(8)28(8)4(6)
Li1368(7)89(15)29(8)11(9)-2(6)-4(8)
Li14110(30)39(15)80(20)2(14)40(20)8(15)
Li1561(7)78(10)84(9)8(7)20(7)44(7)
I132.71(10)38.28(9)39.89(9)-1.43(4)8.10(7)-1.72(4)
S129.3(2)34.7(2)38.2(2)-0.53(18)9.45(18)-4.40(17)
S233.5(3)47.5(3)25.5(2)1.76(15)3.86(19)5.79(17)
S343.3(3)24.87(19)39.0(2)-2.88(17)11.8(2)-0.43(18)
S428.5(2)30.0(2)24.50(19)0.52(13)5.99(16)4.11(14)
S527.4(2)32.7(2)32.8(2)-1.96(15)4.23(17)-3.94(16)
S634.3(3)40.9(3)28.9(2)-1.64(15)11.3(2)3.71(16)
S739.8(3)23.60(18)34.8(2)1.51(15)9.18(19)-1.51(16)

 

Table 4 Bond Lengths for MJR_RA_553_500K.
AtomAtomLength/Å AtomAtomLength/Å
Si1S12.0982(7) Li6S322.452(15)
Si1S22.0988(7) Li7Li1263.068(12)
Si1S32.0923(6) Li7Li1521.23(4)
Si1S42.1961(6) Li7I122.885(9)
Si2S42.1965(6) Li7S122.577(11)
Si2S52.1006(7) Li7S22.470(8)
Si2S62.0970(7) Li7S322.532(11)
Si2S72.0929(6) Li8Li891.33(3)
Li1Li22.952(7) Li8Li962.944(18)
Li1Li313.035(8) Li8Li932.984(19)
Li1Li723.331(11) Li8Li1092.30(2)
Li1Li1033.125(11) Li8Li1193.21(2)
Li1Li1412.64(4) Li8Li1492.63(5)
Li1Li152.80(4) Li8Li141.35(4)
Li1I12.890(4) Li8S592.641(13)
Li1S112.682(5) Li8S52.410(12)
Li1S32.575(4) Li8S692.506(13)
Li1S412.882(5) Li8S762.486(12)
Li1S512.677(5) Li9Li103.33(2)
Li1S72.580(5) Li9Li1130.854(18)
Li2S32.447(6) Li9Li1433.17(4)
Li2S412.904(6) Li9S242.605(12)
Li2S642.467(5) Li9S443.003(13)
Li2S72.459(5) Li9S532.693(13)
Li3Li723.187(14) Li9S612.700(19)
Li3Li1033.350(13) Li9S72.434(12)
Li3I153.050(8) Li10Li1132.56(3)
Li3I163.269(7) Li10Li13103.09(3)
Li3I12.871(6) Li10Li1491.21(4)
Li3S12.475(8) Li10I132.771(10)
Li3S52.469(7) Li10S532.573(12)
Li4Li471.98(4) Li10S62.385(9)
Li4Li572.88(2) Li10S732.491(10)
Li4Li52.93(2) Li11Li13112.92(3)
Li4Li722.08(2) Li11S2122.544(13)
Li4Li120.988(19) Li11S52.537(15)
Li4Li151.10(4) Li11S632.66(2)
Li4Li1573.00(5) Li11S732.551(15)
Li4S112.427(13) Li12Li1572.03(4)
Li4S122.621(16) Li12Li152.03(4)
Li4S222.477(13) Li12S112.3249(5)
Li4S32.394(14) Li12S122.3249(5)
Li5Li621.02(3) Li12S213.0004(6)
Li5Li73.23(2) Li12S223.0004(6)
Li5Li1183.49(3) Li12S372.9312(5)
Li5Li122.73(2) Li12S32.9312(5)
Li5Li130.69(3) Li13I182.94(2)
Li5Li1573.13(3) Li13S212.52(3)
Li5I182.800(17) Li13S32.38(3)
Li5S122.71(2) Li13S642.66(3)
Li5S212.63(2) Li14I162.99(4)
Li5S32.393(17) Li14S52.44(3)
Li6Li722.31(3) Li14S692.32(4)
Li6Li1263.171(15) Li14S762.36(4)
Li6Li1321.46(4) Li15I13.08(4)
Li6Li153.30(4) Li15S112.51(3)
Li6I152.777(12) Li15S222.42(3)
Li6S12.580(18) Li15S32.30(3)
Li6S222.553(16)    

1+X,1+Y,+Z; 21-X,1-Y,1-Z; 31-X,1-Y,-Z; 43/2-X,1/2+Y,1/2-Z; 51/2-X,-1/2+Y,1/2-Z; 6+X,-1+Y,+Z; 71-X,2-Y,1-Z; 81/2+X,3/2-Y,1/2+Z; 91-X,-Y,-Z; 103/2-X,-1/2+Y,1/2-Z; 11-1/2+X,3/2-Y,-1/2+Z; 12-1/2+X,1/2-Y,-1/2+Z

 

Table 5 Bond Angles for MJR_RA_553_500K.
AtomAtomAtomAngle/˚ AtomAtomAtomAngle/˚
S1Si1S2113.79(3) Li103Li11Li8990.2(6)
S1Si1S4108.89(3) Li103Li11Li131168.4(8)
S2Si1S4102.23(3) Li103Li11S6354.3(5)
S3Si1S1110.15(3) Li1311Li11Si2396.9(9)
S3Si1S2110.72(3) Li1311Li11Li5116.8(8)
S3Si1S4110.82(3) Li1311Li11Li8153.9(8)
S5Si2S4108.76(3) Li1311Li11Li89158.6(10)
S6Si2S4101.96(3) S212Li11Si23145.5(6)
S6Si2S5112.44(3) S212Li11Li51148.7(4)
S7Si2S4109.59(2) S212Li11Li89135.9(7)
S7Si2S5113.75(3) S212Li11Li8113.0(6)
S7Si2S6109.67(3) S212Li11Li103106.6(8)
Li2Li1Li31155.8(3) S212Li11Li131154.4(7)
Li2Li1Li7298.7(2) S212Li11S63110.1(7)
Li2Li1Li103100.2(2) S212Li11S73149.3(10)
Li31Li1Li7295.6(2) S5Li11Si23109.1(6)
Li31Li1Li10398.6(3) S5Li11Li511107.0(7)
Li103Li1Li7292.5(3) S5Li11Li844.7(3)
Li141Li1Li2105.8(8) S5Li11Li8953.2(3)
Li141Li1Li3186.5(8) S5Li11Li10360.6(5)
Li141Li1Li72112.4(9) S5Li11Li1311111.1(9)
Li141Li1Li10322.4(8) S5Li11S212100.0(5)
Li141Li1Li15129.4(12) S5Li11S63113.4(9)
Li141Li1I165.2(9) S5Li11S73100.5(5)
Li141Li1S11137.3(8) S63Li11Si2341.1(2)
Li141Li1S41114.4(9) S63Li11Li51163.1(6)
Li141Li1S5154.6(7) S63Li11Li8134.3(6)
Li15Li1Li2102.1(6) S63Li11Li89112.7(6)
Li15Li1Li3184.7(5) S63Li11Li131156.7(8)
Li15Li1Li7220.9(7) S73Li11Si2341.28(19)
Li15Li1Li103111.7(8) S73Li11Li511141.9(7)
Li15Li1I165.6(8) S73Li11Li8949.6(4)
Li15Li1S41116.1(8) S73Li11Li868.5(5)
I1Li1Li2137.07(19) S73Li11Li103103.3(6)
I1Li1Li3166.93(19) S73Li11Li1311135.1(8)
I1Li1Li7254.7(2) S73Li11S6382.1(4)
I1Li1Li10354.7(2) Li47Li12Li4180.0
S11Li1Li2114.88(19) Li4Li12Li5788.3(9)
S11Li1Li3150.86(17) Li47Li12Li588.3(9)
S11Li1Li7274.7(2) Li4Li12Li591.7(9)
S11Li1Li103143.9(2) Li47Li12Li5791.7(9)
S11Li1Li1554.4(6) Li47Li12Li15714.1(12)
S11Li1I191.72(13) Li4Li12Li157165.9(12)
S11Li1S4177.71(12) Li4Li12Li1514.1(12)
S3Li1Li252.02(13) Li47Li12Li15165.9(12)
S3Li1Li31132.3(2) Li47Li12S1196.1(8)
S3Li1Li7248.73(18) Li47Li12S1283.9(8)
S3Li1Li103111.4(2) Li4Li12S1296.1(8)
S3Li1Li141132.0(7) Li4Li12S1183.9(8)
S3Li1Li1550.4(5) Li47Li12S2149.6(7)
S3Li1I1101.03(15) Li4Li12S2249.6(7)
S3Li1S1185.62(13) Li47Li12S22130.4(7)
S3Li1S4191.18(14) Li4Li12S21130.4(7)
S3Li1S51169.0(2) Li47Li12S3131.5(8)
S3Li1S789.74(14) Li4Li12S348.5(8)
S41Li1Li259.67(14) Li4Li12S37131.5(8)
S41Li1Li3196.4(2) Li47Li12S3748.5(8)
S41Li1Li72132.2(2) Li57Li12Li5180.0
S41Li1Li103130.9(2) Li57Li12S21125.5(4)
S41Li1I1163.25(17) Li57Li12S2254.5(4)
S51Li1Li2120.1(2) Li5Li12S2154.5(4)
S51Li1Li3150.75(15) Li5Li12S22125.5(4)
S51Li1Li72140.9(2) Li57Li12S3130.2(4)
S51Li1Li10376.4(2) Li5Li12S349.8(4)
S51Li1Li15135.3(5) Li57Li12S3749.8(4)
S51Li1I189.86(13) Li5Li12S37130.2(4)
S51Li1S1192.28(14) Li157Li12Li5799.3(8)
S51Li1S4177.78(12) Li15Li12Li5780.7(8)
S7Li1Li252.25(13) Li15Li12Li599.3(8)
S7Li1Li31137.3(2) Li157Li12Li580.7(8)
S7Li1Li72112.3(2) Li157Li12Li15180.0
S7Li1Li10350.7(2) Li15Li12S12110.1(9)
S7Li1Li14153.7(8) Li157Li12S1269.9(9)
S7Li1Li15130.6(6) Li157Li12S11110.1(9)
S7Li1I1103.02(15) Li15Li12S1169.9(9)
S7Li1S11165.15(19) Li15Li12S21126.7(9)
S7Li1S4188.31(13) Li157Li12S2153.3(9)
S7Li1S5189.59(14) Li157Li12S22126.7(9)
S3Li2S4193.32(19) Li15Li12S2253.3(9)
S3Li2S64100.8(2) Li157Li12S3751.3(7)
S3Li2S795.67(18) Li15Li12S37128.7(7)
S64Li2S41103.56(17) Li157Li12S3128.7(7)
S7Li2S4190.19(17) Li15Li12S351.3(7)
S7Li2S64157.7(3) S11Li12Li5764.1(4)
Li15Li3Li72105.6(3) S11Li12Li5115.9(4)
Li15Li3Li103102.3(3) S12Li12Li564.1(4)
Li15Li3I1554.40(13) S12Li12Li57115.9(4)
Li15Li3I16120.7(2) S12Li12S11180.000(17)
Li72Li3Li10391.0(3) S12Li12S2198.438(17)
Li72Li3I15134.1(3) S12Li12S2281.562(17)
I1Li3Li15143.6(3) S11Li12S2181.562(17)
I1Li3Li7256.6(2) S11Li12S2298.438(17)
I16Li3Li7276.8(2) S12Li12S395.182(16)
I15Li3Li103130.8(3) S11Li12S3795.182(16)
I16Li3Li103137.0(3) S12Li12S3784.818(16)
I1Li3Li10352.2(2) S11Li12S384.818(16)
I1Li3I15161.2(3) S22Li12S21180.0
I16Li3I1581.24(18) S3Li12S2183.035(14)
I1Li3I1688.08(18) S3Li12S2296.965(14)
S1Li3Li1557.16(16) S37Li12S2283.034(14)
S1Li3Li7252.3(2) S37Li12S2196.966(14)
S1Li3Li103117.8(4) S37Li12S3179.999(14)
S1Li3I1687.0(2) Li2Li13Li47113.3(8)
S1Li3I1587.12(16) Li2Li13Li491.4(7)
S1Li3I1107.9(3) Li2Li13Li10497.2(9)
S5Li3Li1557.08(16) Li2Li13Li12102.6(7)
S5Li3Li72120.2(4) Li47Li13Li434.7(7)
S5Li3Li10349.7(2) Li5Li13Li2134(3)
S5Li3I16163.0(3) Li5Li13Li449(3)
S5Li3I1101.8(2) Li5Li13Li4749(3)
S5Li3I1585.34(18) Li5Li13Li6238(3)
S5Li3S1102.8(3) Li5Li13Li104126(3)
Si12Li4Li15785.6(8) Li5Li13Li118143(4)
Li47Li4Si1292.9(8) Li5Li13Li1247(3)
Li47Li4Li568.6(9) Li5Li13I1871(3)
Li47Li4Li5771.6(9) Li5Li13S2192(4)
Li47Li4Li72177.4(11) Li5Li13S383(3)
Li47Li4Li1579.5(8) Li5Li13S64155(4)
Li47Li4S1172.3(8) Li62Li13Li2114.4(16)
Li47Li4S1261.9(8) Li62Li13Li4785.7(16)
Li47Li4S22112.7(9) Li62Li13Li469.7(13)
Li47Li4S3113.5(10) Li62Li13Li104113.2(14)
Li5Li4Si1296.9(6) Li62Li13Li118163.0(16)
Li57Li4Si1285.0(5) Li62Li13Li1277.2(15)
Li57Li4Li5140.3(7) Li62Li13I1868.9(9)
Li5Li4Li15763.7(7) Li62Li13S21131(2)
Li57Li4Li15777.0(7) Li62Li13S375.0(12)
Li72Li4Si1284.6(5) Li62Li13S64117.7(19)
Li72Li4Li5112.4(8) Li104Li13Li4168.4(12)
Li72Li4Li57107.3(7) Li104Li13Li47133.8(11)
Li72Li4Li157168.9(9) Li104Li13Li12151.3(12)
Li72Li4S11109.4(7) Li118Li13Li275.6(7)
Li72Li4S12116.5(6) Li118Li13Li47103.4(11)
Li72Li4S2264.9(5) Li118Li13Li4125.5(11)
Li72Li4S368.5(5) Li118Li13Li10450.3(7)
Li12Li4Si1292.9(8) Li118Li13Li12115.3(11)
Li12Li4Li470.001(3) Li118Li13I1895.0(9)
Li12Li4Li5771.6(9) Li12Li13Li4717.5(4)
Li12Li4Li568.6(9) Li12Li13Li417.2(3)
Li12Li4Li72177.4(11) I18Li13Li2145.6(12)
Li12Li4Li1579.5(8) I18Li13Li47101.0(9)
Li12Li4Li15153(2) I18Li13Li4119.8(9)
Li12Li4S1172.3(8) I18Li13Li10454.6(5)
Li12Li4S1261.9(8) I18Li13Li12111.2(9)
Li12Li4S22112.7(9) S21Li13Li2102.0(8)
Li12Li4S3113.5(10) S21Li13Li4748.4(7)
Li15Li4Si12108(2) S21Li13Li477.4(8)
Li15Li4Li47153(2) S21Li13Li10493.1(9)
Li15Li4Li5123.6(17) S21Li13Li11855.2(7)
Li15Li4Li5792.8(15) S21Li13Li1262.6(7)
Li15Li4Li7228.2(18) S21Li13I1899.0(9)
Li15Li4Li157162.8(15) S21Li13S64111.1(11)
Li15Li4S1181.2(19) S3Li13Li251.5(5)
Li15Li4S12145(2) S3Li13Li4778.9(9)
Li15Li4S2274.0(19) S3Li13Li445.8(6)
Li15Li4S371.6(15) S3Li13Li104145.2(13)
S12Li4Si1243.9(2) S3Li13Li118120.5(9)
S11Li4Si12145.2(6) S3Li13Li1262.0(7)
S11Li4Li5106.0(6) S3Li13I18143.8(12)
S11Li4Li5760.6(5) S3Li13S21106.8(10)
S12Li4Li57102.5(6) S3Li13S6497.3(10)
S12Li4Li558.0(5) S64Li13Li250.4(5)
S12Li4Li15752.4(8) S64Li13Li47154.8(10)
S11Li4Li15781.7(7) S64Li13Li4141.5(9)
S11Li4S12134.1(8) S64Li13Li10448.3(5)
S11Li4S22111.6(6) S64Li13Li11856.8(7)
S22Li4Si1244.56(19) S64Li13Li12152.1(8)
S22Li4Li5140.8(7) S64Li13I1896.5(9)
S22Li4Li5758.4(5) Li15Li14Li93115.4(11)
S22Li4Li157110.8(8) Li15Li14Li1312114.5(13)
S22Li4S1287.1(4) Li15Li14I1561.4(8)
S3Li4Si12119.2(6) Li89Li14Li15108.6(14)
S3Li4Li57154.0(7) Li8Li14Li15111(2)
S3Li4Li552.2(5) Li8Li14Li8911.4(11)
S3Li4Li157112.3(7) Li8Li14Li9369.8(15)
S3Li4S12102.1(5) Li89Li14Li9360.2(8)
S3Li4S1195.7(4) Li8Li14Li1312130(2)
S3Li4S22131.5(8) Li89Li14Li1312125.7(14)
Li47Li5Li439.7(8) Li89Li14I15154.0(13)
Li47Li5Li799.0(7) Li8Li14I15165(2)
Li4Li5Li779.4(6) Li8Li14S572.6(15)
Li4Li5Li118119.6(7) Li8Li14S6981.5(18)
Li47Li5Li11899.2(7) Li8Li14S7579.1(19)
Li47Li5Li15720.5(6) Li93Li14Li131272.1(10)
Li4Li5Li15759.2(9) Li109Li14Li15102(2)
Li62Li5Li47119.2(16) Li109Li14Li89137(2)
Li62Li5Li492.4(13) Li109Li14Li8127(3)
Li62Li5Li721.5(13) Li109Li14Li93130(2)
Li62Li5Li118141.6(18) Li109Li14Li131261.8(18)
Li62Li5Li12106.2(14) Li109Li14I1568.0(17)
Li62Li5Li157122.2(18) Li109Li14S5160(3)
Li62Li5I1878.2(11) Li109Li14S6978.0(18)
Li62Li5S1272.0(14) Li109Li14S7581.6(18)
Li62Li5S21170.7(19) I15Li14Li93100.7(11)
Li62Li5S381.1(13) I15Li14Li131253.6(8)
Li7Li5Li118160.4(8) S5Li14Li1563.4(9)
Li12Li5Li4720.1(4) S5Li14Li8962.6(9)
Li12Li5Li419.7(4) S5Li14Li9355.6(7)
Li12Li5Li789.0(6) S5Li14Li1312110.2(13)
Li12Li5Li118110.5(7) S5Li14I1592.4(11)
Li12Li5Li15739.8(7) S69Li14Li15162.7(18)
Li12Li5I18131.1(7) S69Li14Li8981.3(12)
Li13Li5Li47120(4) S69Li14Li9356.4(8)
Li13Li5Li4120(3) S69Li14Li131249.8(9)
Li13Li5Li62116(5) S69Li14I15103.4(15)
Li13Li5Li7138(4) S69Li14S5111.9(14)
Li13Li5Li11830(4) S69Li14S75134.4(16)
Li13Li5Li12122(3) S75Li14Li1561.8(9)
Li13Li5Li157121(4) S75Li14Li8987.0(14)
Li13Li5I1895(3) S75Li14Li93145.3(16)
Li13Li5S12171(4) S75Li14Li1312142.3(14)
Li13Li5S2173(4) S75Li14I15106.0(13)
Li13Li5S381(3) S75Li14S5101.0(15)
Li157Li5Li7100.7(9) Li1Li15Li47101.7(11)
Li157Li5Li11893.8(9) Li1Li15Li57113.2(10)
I18Li5Li47115.7(7) Li1Li15Li6134.2(12)
I18Li5Li4143.1(8) Li1Li15Li137122.3(10)
I18Li5Li779.7(5) Li1Li15I158.7(7)
I18Li5Li11886.0(6) Li4Li15Li1112(2)
I18Li5Li15795.7(8) Li4Li15Li4717.2(15)
S12Li5Li455.2(5) Li47Li15Li5757.1(7)
S12Li5Li4751.4(4) Li4Li15Li5766.7(15)
S12Li5Li750.5(4) Li47Li15Li6120.6(12)
S12Li5Li118142.7(8) Li4Li15Li6106(2)
S12Li5Li1250.6(4) Li4Li15Li72127(3)
S12Li5Li15750.2(7) Li4Li15Li1212.6(12)
S12Li5I1888.1(5) Li47Li15Li13760.7(8)
S21Li5Li483.6(6) Li4Li15Li13767.5(15)
S21Li5Li4753.2(5) Li4Li15I1164(2)
S21Li5Li7149.3(8) Li47Li15I1146.7(11)
S21Li5Li11846.5(5) Li4Li15S1173.1(19)
S21Li5Li1267.9(5) Li4Li15S2280.1(19)
S21Li5Li15748.6(7) Li4Li15S381.4(17)
S21Li5I1899.9(6) Li57Li15Li6104.7(11)
S21Li5S1298.8(7) Li57Li15Li1379.6(6)
S3Li5Li4787.5(7) Li6Li15Li13795.2(10)
S3Li5Li452.2(5) Li72Li15Li1104.8(18)
S3Li5Li786.6(6) Li72Li15Li47144(2)
S3Li5Li118101.4(7) Li72Li15Li57129.3(19)
S3Li5Li1269.4(5) Li72Li15Li629.4(11)
S3Li5Li157108.0(9) Li72Li15Li12139(2)
S3Li5I18154.5(9) Li72Li15Li137120.6(18)
S3Li5S1299.7(7) Li72Li15I169.3(16)
S3Li5S21102.8(6) Li72Li15S11160(2)
Si12Li6Li45112.0(5) Li72Li15S2277.9(16)
Si12Li6Li4278.9(4) Li72Li15S386.2(12)
Si12Li6Li12596.4(4) Li12Li15Li1104.7(14)
Si12Li6Li1566.1(7) Li12Li15Li474.6(4)
Li42Li6Li4534.2(6) Li12Li15Li5759.5(8)
Li42Li6Li12518.0(4) Li12Li15Li6116.6(14)
Li42Li6Li1594.2(7) Li12Li15Li13762.3(8)
Li52Li6Si12116.5(15) Li12Li15I1151.3(14)
Li52Li6Li4268.7(13) Li12Li15S1160.6(9)
Li52Li6Li4546.1(14) Li12Li15S2284.4(12)
Li52Li6Li72149.2(18) Li12Li15S385.0(12)
Li52Li6Li12555.8(13) I1Li15Li57103.2(8)
Li52Li6Li13225.0(19) I1Li15Li688.9(10)
Li52Li6Li15160.8(17) I1Li15Li137104.7(8)
Li52Li6I1680.8(11) S11Li15Li160.4(8)
Li52Li6S186.0(15) S11Li15Li4756.0(7)
Li52Li6S22148.9(19) S11Li15Li5756.1(6)
Li52Li6S3274.7(13) S11Li15Li6160.1(11)
Li72Li6Si1279.9(5) S11Li15Li13765.7(8)
Li72Li6Li4291.1(6) S11Li15I190.9(10)
Li72Li6Li45104.7(7) S22Li15Li1159.0(12)
Li72Li6Li12598.6(6) S22Li15Li4786.0(11)
Li72Li6Li1515.1(6) S22Li15Li5754.9(6)
Li72Li6I1698.8(7) S22Li15Li650.2(7)
Li72Li6S163.3(6) S22Li15Li13745.3(6)
Li72Li6S2260.8(5) S22Li15I1104.7(11)
Li72Li6S32109.9(6) S22Li15S11111.0(10)
Li125Li6Li4516.2(3) S3Li15Li159.8(8)
Li125Li6Li15105.4(7) S3Li15Li4786.4(12)
Li132Li6Si12102.8(13) S3Li15Li57141.9(16)
Li132Li6Li4284.4(14) S3Li15Li6103.5(9)
Li132Li6Li4569.6(15) S3Li15Li137147.1(16)
Li132Li6Li72174.2(18) S3Li15I1102.5(12)
Li132Li6Li12576.1(15) S3Li15S1196.0(13)
Li132Li6Li15168.8(15) S3Li15S22140.9(14)
Li132Li6I1681.7(11) Li1I1Li3158.67(17)
Li132Li6S1111.0(16) Li1I1Li313131.13(16)
Li132Li6S22124.6(16) Li1I1Li1311124.6(7)
Li132Li6S3269.8(11) Li1I1Li14153.4(8)
Li15Li6Li45114.7(7) Li1I1Li1555.8(7)
I16Li6Si12147.7(6) Li3I1Li1103.0(2)
I16Li6Li4599.6(5) Li3I1Li31399.4(2)
I16Li6Li42133.3(6) Li313I1Li3191.22(17)
I16Li6Li125115.6(5) Li3I1Li31161.2(3)
I16Li6Li15107.0(9) Li3I1Li7267.3(3)
S1Li6Si12115.9(6) Li3I1Li131188.7(7)
S1Li6Li4253.4(4) Li3I1Li14195.8(6)
S1Li6Li4544.1(3) Li3I1Li1589.6(6)
S1Li6Li12546.3(3) Li313I1Li1581.8(6)
S1Li6Li1576.5(7) Li511I1Li1135.9(4)
S1Li6I1691.1(4) Li511I1Li31385.1(5)
S22Li6Si1243.7(2) Li511I1Li31104.2(4)
S22Li6Li45150.7(6) Li511I1Li392.2(4)
S22Li6Li42117.0(6) Li511I1Li72151.5(5)
S22Li6Li125134.8(5) Li511I1Li131113.5(6)
S22Li6Li1546.6(6) Li511I1Li14184.4(8)
S22Li6I16107.5(5) Li511I1Li15166.9(7)
S22Li6S1122.9(9) Li613I1Li1128.8(3)
S32Li6Si1243.9(2) Li613I1Li31378.2(5)
S32Li6Li4573.8(5) Li613I1Li3184.5(4)
S32Li6Li4248.7(4) Li613I1Li3112.7(4)
S32Li6Li12561.3(3) Li613I1Li51121.0(5)
S32Li6Li15101.0(8) Li613I1Li72157.3(5)
S32Li6I16151.3(9) Li613I1Li131129.4(8)
S32Li6S1101.7(5) Li613I1Li14186.8(8)
S32Li6S2287.1(4) Li613I1Li15152.0(7)
Si12Li7Li1280.8(2) Li72I1Li170.4(2)
Si12Li7Li3276.6(3) Li72I1Li3199.9(3)
Si12Li7Li588.5(4) Li72I1Li31379.5(2)
Li32Li7Li1287.5(3) Li72I1Li1311154.9(7)
Li32Li7Li576.3(4) Li72I1Li141115.9(8)
Li42Li7Si1296.3(5) Li72I1Li1523.5(6)
Li42Li7Li1273.1(5) Li103I1Li167.0(2)
Li42Li7Li32160.3(6) Li103I1Li372.8(3)
Li42Li7Li5122.4(6) Li103I1Li313161.9(3)
Li42Li7Li62117.0(6) Li103I1Li31101.0(3)
Li42Li7Li1250.8(3) Li103I1Li51179.0(5)
Li42Li7I12112.2(6) Li103I1Li61389.6(5)
Li42Li7S12133.7(6) Li103I1Li72111.1(3)
Li42Li7S265.3(4) Li103I1Li131165.5(6)
Li42Li7S3261.6(5) Li103I1Li14124.0(7)
Li5Li7Li12162.3(5) Li103I1Li15113.9(6)
Li62Li7Si1296.7(5) Li1311I1Li31105.1(7)
Li62Li7Li12169.9(6) Li1311I1Li31398.6(6)
Li62Li7Li3282.4(5) Li1311I1Li14171.8(10)
Li62Li7Li59.3(6) Li1311I1Li15178.3(8)
Li62Li7Li125116.2(5) Li141I1Li313161.7(7)
Li62Li7I12118.3(5) Li141I1Li3177.0(6)
Li62Li7S1263.5(5) Li141I1Li15108.3(10)
Li62Li7S264.4(4) Li15I1Li3176.5(6)
Li62Li7S32132.8(5) Si1S1Li1589.27(10)
Li125Li7Si1296.7(3) Si1S1Li3115.97(19)
Li125Li7Li1273.9(3) Si1S1Li45106.3(4)
Li125Li7Li32161.1(4) Si1S1Li4276.2(3)
Li125Li7Li5121.7(4) Si1S1Li52132.1(4)
Li152Li7Si12106.6(13) Si1S1Li6119.9(3)
Li152Li7Li1254.3(16) Si1S1Li7281.6(2)
Li152Li7Li32139.3(17) Si1S1Li12590.69(2)
Li152Li7Li4225.0(16) Si1S1Li155122.2(7)
Li152Li7Li5143.1(16) Li15S1Li52133.6(4)
Li152Li7Li62135.4(16) Li3S1Li1571.99(18)
Li152Li7Li12525.6(16) Li3S1Li42166.4(3)
Li152Li7I1287.2(16) Li3S1Li5299.6(4)
Li152Li7S12149.0(14) Li3S1Li693.4(4)
Li152Li7S273.0(14) Li3S1Li7278.2(3)
Li152Li7S3264.8(13) Li3S1Li155104.4(8)
I12Li7Si12112.6(3) Li45S1Li1582.5(4)
I12Li7Li1254.84(18) Li42S1Li15116.0(4)
I12Li7Li3256.2(2) Li45S1Li3129.4(5)
I12Li7Li5118.4(5) Li45S1Li4245.9(8)
I12Li7Li125112.7(4) Li42S1Li5266.8(5)
S12Li7Si1242.44(13) Li45S1Li5268.0(5)
S12Li7Li12109.6(3) Li45S1Li688.3(5)
S12Li7Li3249.5(2) Li45S1Li72136.5(4)
S12Li7Li554.2(4) Li45S1Li15525.7(8)
S12Li7Li125133.8(4) Li6S1Li15150.8(3)
S12Li7I12104.7(3) Li6S1Li4274.4(5)
S2Li7Si12138.1(4) Li6S1Li5222.0(6)
S2Li7Li12123.6(4) Li72S1Li15141.0(2)
S2Li7Li32131.6(5) Li72S1Li4298.6(4)
S2Li7Li573.5(4) Li72S1Li5275.3(5)
S2Li7Li12564.5(2) Li72S1Li653.3(5)
S2Li7I12109.2(3) Li125S1Li15100.33(10)
S2Li7S12126.6(4) Li125S1Li3151.58(18)
S2Li7S32125.2(5) Li125S1Li4523.9(4)
S32Li7Si1242.45(13) Li125S1Li4222.0(4)
S32Li7Li1249.9(2) Li125S1Li5265.3(4)
S32Li7Li32103.1(3) Li125S1Li680.4(4)
S32Li7Li5126.8(5) Li125S1Li72117.5(2)
S32Li7Li12562.3(3) Li125S1Li15549.5(8)
S32Li7I12102.2(3) Li155S1Li1565.2(8)
S32Li7S1284.5(3) Li155S1Li4271.5(10)
Si29Li8Li11981.5(5) Li155S1Li5273.7(8)
Li89Li8Si2991.6(10) Li155S1Li695.7(8)
Li89Li8Li9375.3(10) Li155S1Li72148.9(7)
Li89Li8Li9578.7(12) Si1S2Li4279.5(4)
Li89Li8Li109170.2(13) Si1S2Li55111.8(4)
Li89Li8Li11987.7(12) Si1S2Li6279.2(3)
Li89Li8Li14911.5(11) Si1S2Li797.3(2)
Li89Li8Li14157(2) Si1S2Li91091.8(3)
Li89Li8S5965.3(10) Si1S2Li1114103.2(5)
Li89Li8S584.5(10) Si1S2Li12573.95(2)
Li89Li8S69111.0(11) Si1S2Li135109.5(5)
Li89Li8S75125.7(13) Si1S2Li15298.9(7)
Li93Li8Si2986.8(4) Li42S2Li5568.4(6)
Li95Li8Si2994.0(5) Li42S2Li6296.3(6)
Li95Li8Li93154.0(6) Li42S2Li910164.2(5)
Li93Li8Li119159.0(7) Li42S2Li1114151.7(6)
Li95Li8Li11915.2(3) Li42S2Li12517.7(4)
Li109Li8Si2979.6(5) Li42S2Li13582.1(8)
Li109Li8Li9399.4(6) Li55S2Li12557.6(4)
Li109Li8Li95106.3(6) Li62S2Li55158.1(6)
Li109Li8Li11995.5(6) Li62S2Li91095.0(7)
Li109Li8Li149164.8(9) Li62S2Li125111.1(4)
Li109Li8S59109.8(6) Li7S2Li4249.8(5)
Li109Li8S5100.0(6) Li7S2Li55103.9(5)
Li109Li8S6959.4(4) Li7S2Li6254.8(6)
Li109Li8S7562.6(4) Li7S2Li910145.5(5)
Li14Li8Si2999.1(17) Li7S2Li1114152.9(4)
Li149Li8Si2986.2(9) Li7S2Li12567.4(3)
Li14Li8Li9385.1(17) Li7S2Li135119.0(7)
Li149Li8Li9385.1(9) Li910S2Li55103.3(6)
Li149Li8Li9569.0(10) Li910S2Li125146.7(4)
Li14Li8Li95120.3(18) Li1114S2Li5584.8(7)
Li14Li8Li10925.0(15) Li1114S2Li62111.9(7)
Li14Li8Li119113.8(17) Li1114S2Li91019.0(4)
Li149Li8Li11976.8(9) Li1114S2Li125135.4(4)
Li14Li8Li149168.6(11) Li135S2Li5515.2(6)
Li149Li8S5955.2(8) Li135S2Li62170.6(7)
Li14Li8S59134.4(17) Li135S2Li91088.5(8)
Li14Li8S575.1(15) Li135S2Li111470.4(9)
Li14Li8S6966.4(18) Li135S2Li12569.2(7)
Li14Li8S7568.7(17) Li152S2Li4225.9(9)
S5Li8Si29145.2(5) Li152S2Li5576.5(8)
S59Li8Si2942.68(17) Li152S2Li6283.2(9)
S5Li8Li95118.8(6) Li152S2Li729.1(8)
S59Li8Li93110.2(5) Li152S2Li910168.6(9)
S59Li8Li9557.3(4) Li152S2Li1114155.2(8)
S5Li8Li9358.8(4) Li152S2Li12542.3(9)
S59Li8Li11950.3(4) Li152S2Li13591.7(10)
S5Li8Li119132.6(6) Si1S3Li1125.64(10)
S5Li8Li14994.8(8) Si1S3Li296.73(14)
S5Li8S59149.8(7) Si1S3Li4120.5(3)
S5Li8S69106.7(5) Si1S3Li5104.7(5)
S5Li8S7598.3(4) Si1S3Li6281.7(4)
S69Li8Si2943.10(18) Si1S3Li7282.8(3)
S69Li8Li9358.1(4) Si1S3Li12131.30(2)
S69Li8Li95134.2(6) Si1S3Li13107.2(8)
S69Li8Li119119.6(6) Si1S3Li15111.2(9)
S69Li8Li149112.8(10) Li1S3Li1288.52(10)
S69Li8S5985.3(3) Li2S3Li171.96(16)
S75Li8Si29111.7(4) Li2S3Li62105.8(5)
S75Li8Li9552.4(4) Li2S3Li72146.9(2)
S75Li8Li93149.6(6) Li2S3Li12129.03(13)
S75Li8Li11951.3(3) Li4S3Li185.5(4)
S75Li8Li149118.8(10) Li4S3Li2142.7(4)
S75Li8S5999.4(4) Li4S3Li6280.9(6)
S75Li8S69119.6(6) Li4S3Li7249.9(5)
Li81Li9Li8326.0(6) Li4S3Li1218.0(4)
Li81Li9Li1081.6(5) Li5S3Li1128.8(5)
Li83Li9Li1092.4(5) Li5S3Li295.6(5)
Li81Li9Li14350.8(9) Li5S3Li475.6(7)
Li83Li9Li14325.1(7) Li5S3Li6224.2(6)
Li83Li9S44144.5(7) Li5S3Li72116.7(5)
Li81Li9S44138.2(5) Li5S3Li1260.8(5)
Li113Li9Li81100.2(14) Li62S3Li1152.6(4)
Li113Li9Li83114.2(15) Li62S3Li72106.9(5)
Li113Li9Li1022.1(14) Li62S3Li1271.6(4)
Li113Li9Li143118.7(17) Li72S3Li181.4(2)
Li113Li9S2476.5(12) Li72S3Li1267.9(2)
Li113Li9S4498.3(17) Li13S3Li1121.4(7)
Li113Li9S5370.4(14) Li13S3Li278.9(7)
Li113Li9S61164.5(18) Li13S3Li488.7(9)
Li113Li9S788.0(14) Li13S3Li516.6(6)
Li143Li9Li1097.5(8) Li13S3Li6235.2(8)
S24Li9Li83126.8(6) Li13S3Li72133.1(8)
S24Li9Li81148.2(6) Li13S3Li1272.1(8)
S24Li9Li1086.3(5) Li15S3Li169.8(9)
S24Li9Li143102.4(9) Li15S3Li2141.1(9)
S24Li9S4472.8(3) Li15S3Li427.0(9)
S24Li9S5394.5(4) Li15S3Li5102.5(11)
S24Li9S61105.4(5) Li15S3Li62104.6(10)
S44Li9Li10120.3(6) Li15S3Li7229.0(9)
S44Li9Li143140.9(10) Li15S3Li1243.6(9)
S53Li9Li8155.7(3) Li15S3Li13115.5(13)
S53Li9Li8349.9(3) Si1S4Si2111.82(3)
S53Li9Li1049.2(3) Si1S4Li1582.38(9)
S53Li9Li14348.4(7) Si1S4Li25112.04(11)
S53Li9S44165.1(6) Si1S4Li91079.9(2)
S53Li9S6194.0(5) Si2S4Li1582.08(9)
S61Li9Li8352.0(4) Si2S4Li25116.65(11)
S61Li9Li8169.8(5) Si2S4Li910143.2(3)
S61Li9Li10142.7(5) Li15S4Li2561.36(13)
S61Li9Li14345.7(7) Li15S4Li910134.7(3)
S61Li9S4497.0(5) Li25S4Li91087.6(4)
S7Li9Li8378.1(5) Si2S5Li1589.04(10)
S7Li9Li8154.1(4) Si2S5Li3117.2(2)
S7Li9Li1086.6(5) Si2S5Li8978.9(3)
S7Li9Li143102.9(9) Si2S5Li895.9(4)
S7Li9S24154.4(8) Si2S5Li93131.5(3)
S7Li9S4489.8(4) Si2S5Li10377.7(2)
S7Li9S5399.3(4) Si2S5Li11122.9(4)
S7Li9S6195.0(5) Si2S5Li14117.4(10)
Si23Li10Li1384.6(3) Li15S5Li93132.7(4)
Si23Li10Li3376.3(3) Li3S5Li1572.17(17)
Si23Li10Li988.1(4) Li3S5Li89163.7(4)
Si23Li10Li1310148.7(8) Li3S5Li93101.0(3)
Li13Li10Li3388.2(3) Li3S5Li10383.2(3)
Li13Li10Li9161.2(4) Li3S5Li1195.3(4)
Li89Li10Si2398.7(5) Li89S5Li15107.2(3)
Li89Li10Li1375.2(4) Li8S5Li1582.8(3)
Li89Li10Li33163.1(5) Li8S5Li3137.3(4)
Li89Li10Li9123.1(5) Li8S5Li8930.2(7)
Li89Li10Li113120.5(6) Li8S5Li9371.3(5)
Li89Li10Li1310110.8(8) Li89S5Li9367.0(4)
Li89Li10I13115.9(5) Li8S5Li103132.6(4)
Li89Li10S53137.3(5) Li8S5Li1187.5(6)
Li89Li10S664.7(4) Li8S5Li1432.3(9)
Li89Li10S7362.4(4) Li103S5Li15142.8(2)
Li9Li10Li3373.3(4) Li103S5Li89104.1(4)
Li113Li10Si2395.2(5) Li103S5Li9378.4(5)
Li113Li10Li13164.0(5) Li11S5Li15147.5(5)
Li113Li10Li3376.2(4) Li11S5Li8976.5(5)
Li113Li10Li97.2(4) Li11S5Li9318.5(4)
Li113Li10Li131061.3(7) Li11S5Li10360.1(6)
Li113Li10I13108.3(5) Li14S5Li1561.9(9)
Li113Li10S5359.3(4) Li14S5Li3105.2(10)
Li1310Li10Li13112.3(6) Li14S5Li8962.2(11)
Li1310Li10Li3378.1(7) Li14S5Li9376.0(10)
Li1310Li10Li967.5(6) Li14S5Li103154.2(10)
Li149Li10Si23113.2(18) Li14S5Li1194.5(11)
Li149Li10Li1355.8(17) Si2S6Li21095.42(13)
Li149Li10Li33139.7(17) Si2S6Li8982.2(3)
Li149Li10Li8927.9(18) Si2S6Li95118.7(3)
Li149Li10Li9142.5(17) Si2S6Li10101.1(2)
Li149Li10Li113137.0(17) Si2S6Li11382.3(3)
Li149Li10Li131097.9(19) Si2S6Li1310146.2(6)
Li149Li10I1388.0(18) Si2S6Li149105.3(10)
Li149Li10S53157.2(18) Li210S6Li89158.5(4)
Li149Li10S672.2(18) Li210S6Li9593.3(3)
Li149Li10S7369.5(19) Li210S6Li11391.3(4)
I13Li10Si23116.2(3) Li210S6Li131073.5(5)
I13Li10Li1358.3(2) Li89S6Li9569.8(4)
I13Li10Li3355.0(2) Li89S6Li113109.4(5)
I13Li10Li9110.6(4) Li89S6Li1310119.4(6)
I13Li10Li131060.0(5) Li10S6Li210144.6(3)
S53Li10Si2344.00(17) Li10S6Li8955.9(4)
S53Li10Li13112.3(3) Li10S6Li95105.5(4)
S53Li10Li3347.1(2) Li10S6Li11360.7(5)
S53Li10Li952.4(3) Li10S6Li131075.5(6)
S53Li10Li1310104.8(7) Li113S6Li95157.8(4)
S53Li10I13101.9(4) Li1310S6Li9594.1(7)
S6Li10Si23135.2(4) Li1310S6Li11366.5(7)
S6Li10Li13125.3(5) Li149S6Li210159.2(10)
S6Li10Li33130.0(4) Li149S6Li8932.2(10)
S6Li10Li971.2(4) Li149S6Li9577.8(8)
S6Li10Li11365.0(4) Li149S6Li1029.9(9)
S6Li10Li131056.2(6) Li149S6Li11390.5(9)
S6Li10I13108.3(4) Li149S6Li131088.3(11)
S6Li10S53122.4(4) Si2S7Li1121.98(10)
S6Li10S73124.4(5) Si2S7Li299.01(13)
S73Li10Si2344.19(16) Si2S7Li81121.9(3)
S73Li10Li1353.2(2) Si2S7Li9104.1(5)
S73Li10Li33105.1(3) Si2S7Li10379.8(3)
S73Li10Li9128.2(5) Si2S7Li11385.2(5)
S73Li10Li113134.3(6) Si2S7Li141108.3(8)
S73Li10Li1310164.4(7) Li2S7Li171.70(17)
S73Li10I13108.9(3) Li2S7Li81139.0(3)
S73Li10S5387.8(3) Li2S7Li103140.9(3)
Si23Li11Li511103.6(7) Li2S7Li113109.3(4)
Si23Li11Li8978.0(4) Li81S7Li183.4(3)
Si23Li11Li8100.8(5) Li81S7Li10354.9(4)
Li89Li11Li511158.0(8) Li81S7Li11379.1(5)
Li8Li11Li511148.1(6) Li9S7Li1133.9(5)
Li89Li11Li822.9(6) Li9S7Li2100.9(3)
Li93Li11Si23112.4(16) Li9S7Li8173.5(5)
Li93Li11Li511131.4(15) Li9S7Li103117.5(4)
Li93Li11Li8964.6(13) Li9S7Li11319.5(4)
Li93Li11Li852.7(13) Li103S7Li176.1(3)
Li93Li11Li103150.7(17) Li103S7Li113109.5(5)
Li93Li11Li1311135.1(17) Li113S7Li1152.7(5)
Li93Li11S21284.5(13) Li141S7Li164.5(9)
Li93Li11S591.1(15) Li141S7Li2135.8(9)
Li93Li11S63147.7(18) Li141S7Li8132.2(9)
Li93Li11S7372.5(14) Li141S7Li9105.2(10)
Li103Li11Si2373.7(5) Li141S7Li10328.8(9)
Li103Li11Li51169.7(7) Li141S7Li113107.1(10)
Li103Li11Li898.4(6)     

1+X,1+Y,+Z; 21-X,1-Y,1-Z; 31-X,1-Y,-Z; 43/2-X,1/2+Y,1/2-Z; 5+X,-1+Y,+Z; 61/2-X,-1/2+Y,1/2-Z; 71-X,2-Y,1-Z; 81/2+X,3/2-Y,1/2+Z; 91-X,-Y,-Z; 103/2-X,-1/2+Y,1/2-Z; 11-1/2+X,3/2-Y,-1/2+Z; 12-1/2+X,1/2-Y,-1/2+Z; 131/2-X,1/2+Y,1/2-Z; 141/2+X,1/2-Y,1/2+Z

 

Table 6 Torsion Angles for MJR_RA_553_500K.
ABCDAngle/˚ ABCDAngle/˚
Si11Li4Li12Li596.3(5) Li12Li4Li15S3106(4)
Si11Li4Li12Li52-83.7(5) Li12Li5Li13Li2-61(7)
Si11Li4Li12Li15239(5) Li12Li5Li13Li4-23.0(10)
Si11Li4Li12Li15-141(5) Li12Li5Li13Li4223.4(12)
Si11Li4Li12S13-147.8(4) Li12Li5Li13Li61-133(5)
Si11Li4Li12S1132.2(4) Li12Li5Li13Li108143.7(18)
Si11Li4Li12S23138.8(5) Li12Li5Li13Li11974(5)
Si11Li4Li12S21-41.2(5) Li12Li5Li13I19147(3)
Si11Li4Li12S32-56.3(10) Li12Li5Li13S2348(3)
Si11Li4Li12S3123.7(10) Li12Li5Li13S3-58(3)
Si11Li4Li15Li1-167.8(7) Li12Li5Li13S68-150(6)
Si11Li4Li15Li42138(5) Li144Li8Li14Li15-79(6)
Si11Li4Li15Li5285.6(8) Li144Li8Li14Li840.01(3)
Si11Li4Li15Li6-14.0(14) Li144Li8Li14Li9631(6)
Si11Li4Li15Li71-37(3) Li144Li8Li14Li104156(4)
Si11Li4Li15Li12138(5) Li144Li8Li14Li13774(6)
Si11Li4Li15Li13275.2(8) Li144Li8Li14I15-22(14)
Si11Li4Li15I1139(7) Li144Li8Li14S5-28(6)
Si11Li4Li15S13145.3(8) Li144Li8Li14S6488(6)
Si11Li4Li15S2129.7(9) Li144Li8Li14S75-133(5)
Si11Li4Li15S3-115.7(8) Li15Li4Li12Li5257(5)
Si24Li8Li14Li15163.7(11) Li152Li4Li12Li52-123(5)
Si24Li8Li14Li84-117(6) Li15Li4Li12Li5-123(5)
Si24Li8Li14Li96-85.9(5) Li152Li4Li12Li557(5)
Si24Li8Li14Li10439(4) Li152Li4Li12Li15180.00(2)
Si24Li8Li14Li137-43(2) Li15Li4Li12Li152180.00(3)
Si24Li8Li14I15-139(9) Li152Li4Li12S11-7(5)
Si24Li8Li14S5-144.9(5) Li15Li4Li12S13-7(5)
Si24Li8Li14S64-28.7(9) Li152Li4Li12S13173(5)
Si24Li8Li14S75109.8(7) Li15Li4Li12S11173(5)
Li42Li4Li12Li5233(12) Li152Li4Li12S21-81(5)
Li42Li4Li12Li5-147(12) Li15Li4Li12S23-81(5)
Li42Li4Li12Li152156(15) Li152Li4Li12S2399(5)
Li42Li4Li12Li15-24(15) Li15Li4Li12S2199(5)
Li42Li4Li12S13-31(7) Li152Li4Li12S384(5)
Li42Li4Li12S11149(7) Li152Li4Li12S32-96(5)
Li42Li4Li12S23-104(7) Li15Li4Li12S3-96(5)
Li42Li4Li12S2176(7) Li15Li4Li12S3284(5)
Li42Li4Li12S3261(8) Li152Li4Li15Li154(5)
Li42Li4Li12S3-119(8) Li152Li4Li15Li42-0.001(13)
Li42Li4Li15Li154(5) Li152Li4Li15Li52-53(4)
Li42Li4Li15Li52-53(4) Li152Li4Li15Li6-152(4)
Li42Li4Li15Li6-152(4) Li152Li4Li15Li71-175(3)
Li42Li4Li15Li71-175(3) Li152Li4Li15Li120.00(3)
Li42Li4Li15Li120.00(4) Li152Li4Li15Li132-63(4)
Li42Li4Li15Li132-63(4) Li152Li4Li15I10(12)
Li42Li4Li15I10(12) Li152Li4Li15S137(4)
Li42Li4Li15S137(4) Li152Li4Li15S21-109(4)
Li42Li4Li15S21-109(4) Li152Li4Li15S3106(4)
Li42Li4Li15S3106(4) Li152Li5Li13Li2-108(5)
Li4Li5Li13Li2-38(7) Li152Li5Li13Li42-23.9(13)
Li42Li5Li13Li2-84(6) Li152Li5Li13Li4-70(3)
Li4Li5Li13Li4246(2) Li152Li5Li13Li61179(4)
Li42Li5Li13Li4-46(2) Li152Li5Li13Li10897(4)
Li4Li5Li13Li61-110(4) Li152Li5Li13Li11927(6)
Li42Li5Li13Li61-157(4) Li152Li5Li13Li12-47(2)
Li42Li5Li13Li108120(3) Li152Li5Li13I19100(2)
Li4Li5Li13Li108166.7(12) Li152Li5Li13S231(3)
Li4Li5Li13Li11997(5) Li152Li5Li13S3-105(2)
Li42Li5Li13Li11951(6) Li152Li5Li13S68163(6)
Li42Li5Li13Li12-23.4(12) I19Li5Li13Li2152(4)
Li4Li5Li13Li1223.0(10) I19Li5Li13Li42-124(3)
Li42Li5Li13I19124(3) I19Li5Li13Li4-170(3)
Li4Li5Li13I19170(3) I19Li5Li13Li6179(2)
Li4Li5Li13S2371(3) I19Li5Li13Li108-3(4)
Li42Li5Li13S2325(3) I19Li5Li13Li119-73(5)
Li42Li5Li13S3-82(2) I19Li5Li13Li12-147(3)
Li4Li5Li13S3-35(3) I19Li5Li13S23-98.8(9)
Li42Li5Li13S68-173(6) I19Li5Li13S3154.6(7)
Li4Li5Li13S68-127(7) I19Li5Li13S6863(8)
Li52Li4Li12Li5179.999(3) S13Li4Li12Li5-115.9(4)
Li5Li4Li12Li52180.001(3) S11Li4Li12Li52-115.9(4)
Li5Li4Li12Li152-57(5) S13Li4Li12Li5264.1(4)
Li52Li4Li12Li152123(5) S11Li4Li12Li564.1(4)
Li5Li4Li12Li15123(5) S13Li4Li12Li157(5)
Li52Li4Li12Li15-57(5) S13Li4Li12Li152-173(5)
Li5Li4Li12S11-64.1(4) S11Li4Li12Li15-173(5)
Li52Li4Li12S11115.9(4) S11Li4Li12Li1527(5)
Li5Li4Li12S13115.9(4) S11Li4Li12S13180.000(4)
Li52Li4Li12S13-64.1(4) S13Li4Li12S11180.000(4)
Li52Li4Li12S2142.4(8) S11Li4Li12S23106.6(8)
Li5Li4Li12S2342.4(8) S11Li4Li12S21-73.4(8)
Li5Li4Li12S21-137.6(8) S13Li4Li12S21106.6(8)
Li52Li4Li12S23-137.6(8) S13Li4Li12S23-73.4(8)
Li5Li4Li12S32-152.6(8) S11Li4Li12S32-88.5(7)
Li5Li4Li12S327.4(8) S13Li4Li12S3291.5(7)
Li52Li4Li12S3227.4(8) S11Li4Li12S391.5(7)
Li52Li4Li12S3-152.6(8) S13Li4Li12S3-88.5(7)
Li52Li4Li15Li1106.6(11) S13Li4Li15Li146.9(11)
Li5Li4Li15Li1-57(2) S11Li4Li15Li1-137(2)
Li52Li4Li15Li4253(4) S11Li4Li15Li42169(7)
Li5Li4Li15Li42-110(5) S13Li4Li15Li42-7(4)
Li5Li4Li15Li52-163.1(17) S13Li4Li15Li52-59.7(6)
Li52Li4Li15Li6-99.6(10) S11Li4Li15Li52116(3)
Li5Li4Li15Li697.3(18) S13Li4Li15Li6-159.3(10)
Li5Li4Li15Li7174(4) S11Li4Li15Li617(3)
Li52Li4Li15Li71-123(3) S13Li4Li15Li71178(3)
Li52Li4Li15Li1253(4) S11Li4Li15Li71-6(5)
Li5Li4Li15Li12-110(5) S11Li4Li15Li12169(7)
Li5Li4Li15Li132-173.5(19) S13Li4Li15Li12-7(4)
Li52Li4Li15Li132-10.4(6) S13Li4Li15Li132-70.1(7)
Li52Li4Li15I153(8) S11Li4Li15Li132106(3)
Li5Li4Li15I1-110(7) S11Li4Li15I1169(5)
Li5Li4Li15S13-103.4(15) S13Li4Li15I1-7(8)
Li52Li4Li15S1359.7(6) S11Li4Li15S13176(2)
Li52Li4Li15S21-55.9(7) S13Li4Li15S21-115.6(5)
Li5Li4Li15S21141.0(14) S11Li4Li15S2160(3)
Li52Li4Li15S3158.7(7) S13Li4Li15S399.0(8)
Li5Li4Li15S3-4(2) S11Li4Li15S3-85(3)
Li61Li5Li13Li273(5) S21Li4Li12Li52-42.4(8)
Li61Li5Li13Li42157(4) S21Li4Li12Li5137.6(8)
Li61Li5Li13Li4110(4) S21Li4Li12Li15-99(5)
Li61Li5Li13Li108-83(5) S21Li4Li12Li15281(5)
Li61Li5Li13Li119-152(4) S21Li4Li12S1173.4(8)
Li61Li5Li13Li12133(5) S21Li4Li12S13-106.6(8)
Li61Li5Li13I19-79(2) S21Li4Li12S23180.0
Li61Li5Li13S23-178.2(19) S21Li4Li12S3164.9(14)
Li61Li5Li13S375(2) S21Li4Li12S32-15.1(14)
Li61Li5Li13S68-16(10) S21Li4Li15Li1162.5(14)
Li71Li4Li15Li1-131(3) S21Li4Li15Li42109(4)
Li71Li4Li15Li42175(3) S21Li4Li15Li5255.9(7)
Li71Li4Li15Li52123(3) S21Li4Li15Li6-43.7(8)
Li71Li4Li15Li623(2) S21Li4Li15Li71-67(3)
Li71Li4Li15Li12175(3) S21Li4Li15Li12109(4)
Li71Li4Li15Li132112(3) S21Li4Li15Li13245.5(7)
Li71Li4Li15I1176(10) S21Li4Li15I1109(8)
Li71Li4Li15S13-178(3) S21Li4Li15S13115.6(5)
Li71Li4Li15S2167(3) S21Li4Li15S3-145.4(9)
Li71Li4Li15S3-79(3) S23Li5Li13Li2-109(5)
Li7Li5Li13Li272(6) S23Li5Li13Li42-25(3)
Li7Li5Li13Li42156(6) S23Li5Li13Li4-71(3)
Li7Li5Li13Li4109(5) S23Li5Li13Li61178.2(19)
Li7Li5Li13Li61-1.0(16) S23Li5Li13Li10895(4)
Li7Li5Li13Li108-84(5) S23Li5Li13Li11926(4)
Li7Li5Li13Li119-153(3) S23Li5Li13Li12-48(3)
Li7Li5Li13Li12132(6) S23Li5Li13I1998.8(9)
Li7Li5Li13I19-80(3) S23Li5Li13S3-106.6(8)
Li7Li5Li13S23-179(3) S23Li5Li13S68162(9)
Li7Li5Li13S374(4) S3Li4Li12Li5-27.4(8)
Li7Li5Li13S68-17(11) S3Li4Li12Li52152.6(8)
Li84Li8Li14Li15-79(6) S3Li4Li12Li1596(5)
Li84Li8Li14Li9631(6) S3Li4Li12Li152-84(5)
Li84Li8Li14Li104156(4) S3Li4Li12S1388.5(7)
Li84Li8Li14Li13774(6) S3Li4Li12S11-91.5(7)
Li84Li8Li14I15-22(14) S3Li4Li12S21-164.9(14)
Li84Li8Li14S5-28(6) S3Li4Li12S2315.1(14)
Li84Li8Li14S6488(6) S3Li4Li12S32180.000(1)
Li84Li8Li14S75-133(5) S3Li4Li15Li1-52.1(9)
Li96Li8Li14Li15-110.4(14) S3Li4Li15Li42-106(4)
Li95Li8Li14Li1564(2) S3Li4Li15Li52-158.7(7)
Li96Li8Li14Li84-31(6) S3Li4Li15Li6101.7(10)
Li95Li8Li14Li84143(6) S3Li4Li15Li7179(2)
Li95Li8Li14Li96174.0(11) S3Li4Li15Li12-106(4)
Li96Li8Li14Li104125(4) S3Li4Li15Li132-169.1(7)
Li95Li8Li14Li104-61(4) S3Li4Li15I1-106(8)
Li95Li8Li14Li137-142.8(16) S3Li4Li15S13-99.0(8)
Li96Li8Li14Li13743(2) S3Li4Li15S21145.4(9)
Li96Li8Li14I15-53(9) S3Li5Li13Li2-2(4)
Li95Li8Li14I15121(9) S3Li5Li13Li4282(2)
Li96Li8Li14S5-58.9(5) S3Li5Li13Li435(3)
Li95Li8Li14S5115.0(11) S3Li5Li13Li61-75(2)
Li96Li8Li14S6457.3(7) S3Li5Li13Li108-158(4)
Li95Li8Li14S64-128.8(11) S3Li5Li13Li119133(5)
Li96Li8Li14S75-164.2(8) S3Li5Li13Li1258(3)
Li95Li8Li14S759.7(16) S3Li5Li13I19-154.6(7)
Li104Li8Li14Li15125(4) S3Li5Li13S23106.6(8)
Li104Li8Li14Li84-156(4) S3Li5Li13S68-92(8)
Li104Li8Li14Li96-125(4) S5Li8Li14Li15-51.4(12)
Li104Li8Li14Li137-82(4) S54Li8Li14Li15136.0(13)
Li104Li8Li14I15-178(13) S54Li8Li14Li84-145(7)
Li104Li8Li14S5176(4) S5Li8Li14Li8428(6)
Li104Li8Li14S64-68(3) S5Li8Li14Li9658.9(5)
Li104Li8Li14S7571(3) S54Li8Li14Li96-113.7(18)
Li119Li5Li13Li2-135(8) S54Li8Li14Li10411(5)
Li119Li5Li13Li42-51(6) S5Li8Li14Li104-176(4)
Li119Li5Li13Li4-97(5) S54Li8Li14Li137-70(3)
Li119Li5Li13Li61152(4) S5Li8Li14Li137102(2)
Li119Li5Li13Li10869(4) S5Li8Li14I156(9)
Li119Li5Li13Li12-74(5) S54Li8Li14I15-166(8)
Li119Li5Li13I1973(5) S54Li8Li14S5-172.6(16)
Li119Li5Li13S23-26(4) S5Li8Li14S64116.2(9)
Li119Li5Li13S3-133(5) S54Li8Li14S64-56(2)
Li119Li5Li13S68136(11) S54Li8Li14S7582(2)
Li114Li8Li14Li1579.0(17) S5Li8Li14S75-105.3(9)
Li114Li8Li14Li84158(6) S64Li8Li14Li15-167.6(19)
Li114Li8Li14Li96-170.6(10) S64Li8Li14Li84-88(6)
Li114Li8Li14Li104-46(4) S64Li8Li14Li96-57.3(7)
Li114Li8Li14Li137-127.3(18) S64Li8Li14Li10468(3)
Li114Li8Li14I15137(9) S64Li8Li14Li137-14.0(15)
Li114Li8Li14S5130.5(9) S64Li8Li14I15-110(10)
Li114Li8Li14S64-113.3(11) S64Li8Li14S5-116.2(9)
Li114Li8Li14S7525.2(14) S64Li8Li14S75138.5(11)
Li12Li4Li15Li154(5) S75Li8Li14Li1553.9(13)
Li12Li4Li15Li42-0.001(17) S75Li8Li14Li84133(5)
Li12Li4Li15Li52-53(4) S75Li8Li14Li96164.2(8)
Li12Li4Li15Li6-152(4) S75Li8Li14Li104-71(3)
Li12Li4Li15Li71-175(3) S75Li8Li14Li137-152(2)
Li12Li4Li15Li132-63(4) S75Li8Li14I15111(10)
Li12Li4Li15I10(12) S75Li8Li14S5105.3(9)
Li12Li4Li15S137(4) S75Li8Li14S64-138.5(11)
Li12Li4Li15S21-109(4)      

11-X,1-Y,1-Z; 21-X,2-Y,1-Z; 3+X,1+Y,+Z; 41-X,-Y,-Z; 5+X,-1+Y,+Z; 61-X,1-Y,-Z; 7-1/2+X,1/2-Y,-1/2+Z; 83/2-X,1/2+Y,1/2-Z; 91/2+X,3/2-Y,1/2+Z

 

Table 7 Atomic Occupancy for MJR_RA_553_500K.
AtomOccupancy AtomOccupancy AtomOccupancy
Li10.976(4) Li30.894(4) Li40.340(4)
Li50.368(4) Li60.296(4) Li70.472(4)
Li80.483(4) Li90.56(2) Li100.503(4)
Li110.44(2) Li120.161(7) Li130.221(4)
Li140.167(4) Li150.200(4)   

Experimental

Single crystals of ILi7S7Si2 [MJR_RA_553_500K] were []. A suitable crystal was selected and [] on a dectris-CrysAlisPro-abstract goniometer imported dectris images diffractometer. The crystal was kept at 500.0 K during data collection. Using Olex2 [1], the structure was solved with the SHELXT [2] structure solution program using Intrinsic Phasing and refined with the SHELXL [3] refinement package using Least Squares minimisation.

  1. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H. (2009), J. Appl. Cryst. 42, 339-341.
  2. Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
  3. Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.

Crystal structure determination of [MJR_RA_553_500K]

Crystal Data for ILi7S7Si2 (=456.08 g/mol): monoclinic, space group P21/n (no. 14), a = 14.9817(2) Å, b = 6.05780(10) Å, c = 15.1891(2) Å, β = 105.7390(10)°, = 1326.82(3) Å3, Z = 4, T = 500.0 K, μ(synchrotron) = 3.368 mm-1, Dcalc = 2.283 g/cm3, 26423 reflections measured (3.282° ≤ 2Θ ≤ 72.382°), 6367 unique (Rint = 0.0684, Rsigma = 0.0604) which were used in all calculations. The final R1 was 0.0370 (I > 2σ(I)) and wR2 was 0.1030 (all data).

Refinement model description

Number of restraints - 59, number of constraints - unknown.

Details:

1. Uiso/Uaniso restraints and constraints
Uanis(Li8) ≈ Ueq, Uanis(Li6) ≈ Ueq, Uanis(Li12) ≈ Ueq: with sigma
of 0.02 and sigma for terminal atoms of 0.04
2. Rigid body (RIGU) restrains
Li4, Li5, Li15, Li12, Li13, Li6
with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
3. Others
1*[Sof(Li1)]+1*[Sof(Li3)]+1*[Sof(Li4)]+1*[Sof(Li5)]+1*[Sof(Li6)]+1*[Sof(Li7)]+
1*[Sof(Li8)]+1*[Sof(Li10)]+1*[Sof(Li12)]+1*[Sof(Li13)]+1*[Sof(Li14)]+1*
[Sof(Li15)]=5 with esd of 0.0001
1*[Sof(Li9)]+1*[Sof(Li11)]=1 with esd of 0.001

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